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Effects of chain microstructure of butadiene-isoprene copolymers on their glass transition and crystallization

✍ Scribed by Jiang-wei Zhao; Han Zhu; Yi-xian Wu; Wei-wei Zhou; Guan-ying Wu; Ri-wei Xu

Book ID
106280668
Publisher
Institute of Chemistry Chinese Academy of Sciences
Year
2010
Tongue
English
Weight
508 KB
Volume
28
Category
Article
ISSN
0256-7679

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## Abstract Butadiene/isoprene copolymers were prepared using the catalyst system V(acac)~3~‐MAO. The structure of the comonomers is __trans__‐1,4 and the butadiene and isoprene units are statistically distributed along the polymer chain. The attitude of the butadiene sequences to crystallize in th