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Effects of Chain Extension and Branching on the Properties of Poly (Ethylene-Terephthalate)-Organoclay Nanocomposites

โœ Scribed by Keyfoglu, Ali Emrah; Yilmazer, Ulku


Book ID
121205761
Publisher
Cambridge University Press
Year
2004
Weight
67 KB
Volume
856
Category
Article
ISSN
0272-9172

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A series of branched poly(ethylene terephthalate) samples was prepared by employing 0.07-0.42 mol % trimethylolpropane (TMP) for melt polycondensation. These polymers were characterized with respect to molar mass, intrinsic viscosity, and melt viscosity. Spinning into fibers took place at spinning s

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The effect of branching on the crystallization behavior of poly(ethylene terephthalate) has been examined by nonisothermal crystallization studies, using DSC. It was found that branching causes a significant change in the crystallization behavior, in that the Avrami exponent n lies between 1 and 2,