Effects of calcium stearate addition of ultrahigh molecular weight polyethylene in direct compression molding

✍ Scribed by Masahiro Utsumi; Kazuya Nagata; Masahiko Suzuki; Akiko Mori; Itsuo Sakuramoto; Yuuichi Torigoe; Toshiaki Kaneeda; Hideshige Moriya

• Publisher: John Wiley and Sons
• Year: 2003
• Tongue: English
• Weight: 329 KB
• Volume: 87
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.11584

✦ Synopsis

Abstract

The effects of calcium stearate addition in molding of ultrahigh molecular weight polyethylene (UHMWPE) were investigated by tensile testing, scanning electron microscope (SEM), Fourier transform infrared (FT‐IR) spectroscopy, and elemental analysis. Four types of UHMWPE specimens with varying contents of calcium stearate (<5, 50, 100, and 1000 ppm) were used in this study. SEM observation revealed that calcium stearate added specimens have smoother and more homogeneous microstructures. After accelerated aging, subsurface oxidative degeneration was observed in all specimens; however, calcium stearate added specimens had less oxidative degeneration in comparison with specimens without additives. Specimens showed better mechanical properties with increasing content of calcium stearate. Though all specimens aggravated their mechanical properties due to oxidation after accelerated aging, the specimens of 100 ppm of calcium stearate showed better properties at 3.7 MPa larger yield strength and four times larger value of elongation at fracture than the specimens without additives. These results indicate that calcium stearate addition produces dense packing of UHMWPE particles, which brings about stronger fusion among the particles and fewer structural defects, and results in better mechanical properties and better resistance to oxidative degeneration. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1602–1609, 2003