## Abstract Polyester‐based polyurethanes with embedded nanosilica particles were prepared. The viscosity of polyester resins without and with nanosilica was determined by rheoviscometry. The morphology and mechanical and optical properties of the polyurethane coatings were studied intensively with
Effects of calcium ion on polyester-type polyurethane emulsion and properties of polyurethane film
✍ Scribed by Zhaowen Lou; Jun Luo; Hongju Zhan
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 62 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
Abstract
Polyurethane (PU) emulsions were prepared from polytetramethylene adipate diol, toluene diisocyanate, dimethanol propionic acid, and so forth. The effects of calcium ion on the stability of PU emulsion as well as on the water‐resistance property, tensile strength, and tensile yield of PU film were discussed. The results show that calcium ion can quickly damage the stability of PU emulsion. Meanwhile, calcium ion can distinctly counteract the unfavorable effects water has on the tensile properties of PU film. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1285–1288, 2004
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