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Effects of bond-angle inversion on the statistical properties of poly(dimethylsiloxane)

✍ Scribed by L. C. Debolt; J. E. Mark

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
408 KB
Volume
26
Category
Article
ISSN
0887-6266

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The effect of bond angle on hybridizatio
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THE discovery that the C13-H nuclear spin-spin coupling constant appears to be a linear function of the amount of s-character in the carbon orbital from which a C-H bond is formed1 has made direct estimation of hybridization possible for the first time. In cyclopropanela and certain cyclopropenes2 t