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Effects of alloying substrates on the characteristics of the lithium negative electrode

✍ Scribed by Masayuki Morita; Yoshiharu Matsuda

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
358 KB
Volume
26
Category
Article
ISSN
0378-7753

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✦ Synopsis

Amorphous alloys of Ni,,Al10B2, and Co,sAl,,,Bzo have been used as negative electrode substrates for rechargeable lithium batteries. The chargedischarge behavior of lithium has been investigated at the alloy substrates in some organic electrolytes. The highest cycling efficiency was observed at the amorphous Co,,,Al,,B,, substrate in a mixture of dimethylsulfoxide and propylene carbonate containing LiPF, . The cycling efficiency of this type of substrate depended on the diffusion coefficient of lithium in the alloy as well as on the exchange current for lithium deposition from the organic solution.

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