## Polyaniline deposited on As 2 O 3 surface resulted in a new material, which was characterized by infrared spectoscopy, thermogravimetry, differential scanning calorimetry, scanning electron microscopy, X-ray diffraction, and cyclic voltammetry. The mass percentage of polymer deposited on oxide
Effects of Adsorbed Polyaniline on Redox Process on MoO3Surface
✍ Scribed by Robson F. de Farias; Jucimar M. de Souza; Jailson V. de Melo; Claudio Airoldi
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 235 KB
- Volume
- 212
- Category
- Article
- ISSN
- 0021-9797
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✦ Synopsis
The effects exhibited by adsorbed conducting polyaniline on the redox process on a molybdenum oxide surface were studied. Thermogravimetric results indicate a 4% polyaniline deposition. Cyclic voltammograms of the adsorbed polymer on MoO 3 show that polyaniline exerts remarkable effects on the molybdenum blue oxidation-reduction process, with oxidation and reduction potentials of 0.33 and 0.18 V, respectively. This effect strongly enhances the electrode response, and can be used as an important tool in qualitative and/or quantitative determinations of molybdenum in solution as well as in any substrate.
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