Effects of 5-methyl substitution in 2′-O-methyloligo-(pyrimidine)nucleotides on triple-helix formation

Micellar effects on a ligand substitutio

Micellar effects on a ligand substitution reaction: Kinetics of the formation of [Fe(CN)5(μ-pz)Ru(NH3)5]−, from [Fe(CN)5H2O]3− and [Ru(NH3)5pz]2+, in the presence of anionic micelles

✍ Rafael Jiménez; Elena Bueno; Israel Cano; Elizabeth Corbacho; M. Eugenia Fernánd 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB 👁 2 views

## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3−^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i