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Effective valence-shell hamiltonians generated by canonical transformations

โœ Scribed by E. G. Bradford; Paul Westhaus


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
332 KB
Volume
10
Category
Article
ISSN
0020-7608

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๐Ÿ“œ SIMILAR VOLUMES


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The theoretical many-body structure of the exact effective valence-shell hamiltonian (Xv-) is analyzed to derive experi-mentaIIy observable values of many-electron effective interactions for the [ 2s, 2p] Xv of N, 0, and F, and the [2p 3 JP of F. Unique experimentaI vaIues are presented for four-, f

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The ab initio effective valence shell Hamiltonian method, which is based upon quasidegenerate many-body perturbation theory, has been extended to calculate molecular properties. This new method is applied to the study of dipole moment functions of the OH molecule and its ions. The calculated results