✦ LIBER ✦

Effective two-state systems in bridge-mediated electron transfer: A Green function analysis (Chem. Phys. Letters 209 (1993) 171)

Book ID: 103030204
Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 22 KB
Volume: 211
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85198-w

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✦ Synopsis

On page 176, the last term under the square root I~IM(G"")IZ in equation ( 20), should read I~DA+~D*(G"n)IZ-

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✍ Spiros S. Skourtis; José Nelson Onuchic 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 532 KB

We derived the criteria for the validity of the effective two-state picture of bridge-mediated electron transfer for a one-electron many-state system. The leading error associated with the two-state reduction is calculated. Our Green function analysis connects the time and energy domains. It gives a