Effective rotational potentials for the X1Σ+g state of the H2 molecule

✍ Scribed by A. Pardo

• Publisher: Elsevier Science
• Year: 1994
• Tongue: English
• Weight: 640 KB
• Volume: 50
• Category: Article
• ISSN: 1386-1425
• DOI: 10.1016/0584-8539(94)80143-6

✦ Synopsis

With the spectroscopic constants and RKR procedure, the electronic potential for the ground state of the H2 molecule has been calculated. With the effective potential without rotation we calculate the potential with rotation, for J= 1, 2, 3, 4, 5, 10, 15, 20 and 25. Numerical integration of the radial wave equation gives accurate eigenvalues. The experimental-calculated mean discrepancies are from 0.04 to 0.4 cm-~ between J = 0 and J = 25.