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Effective rotational constants for the three lowest vibrational states of ketene

โœ Scribed by L. Nemes; J. W. C. Johns


Book ID
112998597
Publisher
Springer-Verlag
Year
1994
Tongue
English
Weight
288 KB
Volume
74
Category
Article
ISSN
1219-7580

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Effective rotational Hamiltonian of the
โœ Qing-shi Zhu ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 384 KB

The effective rotational Hamiltonians of the local mode states are derived for XY,, XY, and XY4 molecules by averaging the vibration-rotation Hamiltonians using the corresponding local mode vibrational wavefunctions. The results indicate that in a local mode vibrational state the molecular symmetry