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Effective rate constants and general isotope effect equations for steady state enzymatic reactions with multiple isotope-sensitive steps

✍ Scribed by Gaochao Tian


Book ID
103479343
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
607 KB
Volume
20
Category
Article
ISSN
0045-2068

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Direct ab initio dynamic calculations are performed on the reactions of atomic hydrogen with GeD(n)(CH(3))(4-n) (n = 1-4) over the temperature range 200-2000 K at the PMP4SDTQ/6-311 +G(3df,2p)//MP2/6-31 +G(d) (for n = 2-4) and G2//MP2/6-31 +G(d) (for n = 1) levels. The corresponding k(H)/k(D) ratios