Effective penetration of the barrier in quasi-classical theory of electron transfer
β Scribed by A.I. Burshtein; G.K. Ivanov; M.A. Kozhushner
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 284 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Electron transfer between two centers of location must be, generaIly speaking, treated withb~ the model of muI& tiensronal electron terms. As the temperature and the mter-reagent distance increase. the non-adiabatic transfer me& msm IS replaced by the adxabatic one due to competltlon between high-activated adiabatic transfer channels and low actlMted nonadabaticones
π SIMILAR VOLUMES
Possibility of amplification of electromagnetic radiation is theoretically studied in the scattering of a quasi-classical electron by an ion in the field of weak linearly polarized wave. Using the limiting process of the total cross-section at small values of adiabaticity parameter to Krainov's form
## Abstract The effects of reaction barrier height and initial rotational excitation of the reactants on the overall rate of H atom exchange between atomic chlorine and HCl (__v__ = 0) and on the 0 β 1 vibrational excitation of HCl via reactive and nonreactive collisions have been investigated usin
Electron transfer (ET) is treated as a vibrational quantum mechanical problem in a symmetric Born-Oppenheimer (BO) biparabolic potential of Marcus type, where the distance between the energy minima is given by the reorganization energy Ξ» and force constant k. The interaction is characterized by a ga