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Effective multiple-solvent suppression scheme using the excitation sculpting principle

✍ Scribed by Teodor Parella; Pere Adell; Francisco Sánchez-Ferrando; Albert Virgili


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
197 KB
Volume
36
Category
Article
ISSN
0749-1581

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✦ Synopsis


An interesting and simple approach to e †ective multiple-solvent suppression is proposed using the basic principles of the excitation sculpting methodology. Flat baseline and ultra-clean NMR spectra are usually obtained under standard conditions using a modiÐed double pulsed Ðeld gradient echo scheme in samples containing mixtures of non-deuterated solvents. The simple performance of such an approach, the high tolerance to experimental mis-settings, the impressive level of solvent suppression and the easy incorporation of the proposed scheme in multi-dimensional NMR experiments make this method suitable for possible applications in liquid chromatography NMR.