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Effective coupling of Re/Tc-MAG3complexes with amines and nucleobases in aprotic solvents

✍ Scribed by T. Kniess; S. Noll; B. Noll; H. Spies; B. Johannsen

Book ID
105540517
Publisher
Springer
Year
1999
Tongue
English
Weight
265 KB
Volume
240
Category
Article
ISSN
1588-2780

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Nucleophilic heteroaromatic substitution
Nucleophilic heteroaromatic substitution: Kinetics of the reactions of nitropyridines with aliphatic amines in dipolar aprotic solvents
✍ Chukwuemeka Isanbor; Thomas A. Emokpae 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 256 KB

## Abstract Rate data are reported for the reactions of 2‐chloro‐5‐nitropyridine **2a**, 2‐chloro‐3‐nitropyridine **2b**, and the corresponding 2‐phenoxy derivatives **2c** with __n__‐butylamine, pyrrolidine and piperidine and **2d** with __n__‐butylamine and pyrrolidine in dimethyl sulfoxide (DMSO

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📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 39 KB

line 14: 1-phenoxy should read 2-phenoxy. Page 129, paragraph 3, line 10: the slope of the plot should read the slopes of the plots. Page 134, paragraph 2, lines 2-4: The reaction of pyrrolidine with 2c in acetonitrile is not base-catalyzed whereas that in DMSO is catalyzed should read The reaction