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Effect of Ti substitution for Zr on the thermal expansion property of fluorite-type Gd2Zr2O7

✍ Scribed by Zhan-Guo Liu; Jia-Hu Ouyang; Yu Zhou; Xiao-Liang Xia

Publisher
Elsevier Science
Year
2009
Weight
436 KB
Volume
30
Category
Article
ISSN
0261-3069

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Zr 12x M x W 2 O 82y (M ΒΌ Sc, In and Y) solid solutions substituted up to x ΒΌ 0:04 for Zr(IV) sites by M(III) ions were synthesized by a solid-state reaction. X-ray diffraction experiments from 90 to 560 K revealed that all solid solutions had a cubic crystal structure and showed negative thermal ex