Effect of the X and Y substituents on the carbonyl bond in 4-YC6H4C(O)X compounds
β Scribed by B. A. Suvorov
- Book ID
- 111460948
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 149 KB
- Volume
- 81
- Category
- Article
- ISSN
- 1070-3632
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We report extended basis set SCF treatments of the recently synthesized first stable Al' compound ( AICsR,)4, R = CH3 experimentally, R-H in the calculations. For comparison we consider the series AIX, X=H, F, Cl, C5H,, and its tetramers. Bonding in the tetramers, showing an Al4 tetrahedron, is much
Abstmct: The behaviour towards gas-phase protonation of a series of 2,6-dimethyl-4-X-acetophenones DMl exhibits strong similarities with that of the corresponding 4-X-acetophenones 1. A comparison with previous hasicity data in solution and AM1 semiempirical calculations suggest that the X-dependent