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Effect of the titania morphology on the Au/TiO2-catalyzed aerobic epoxidation of stilbene

✍ Scribed by Pascal Lignier; Massimiliano Comotti; Ferdi Schüth; Jean-Luc Rousset; Valérie Caps

Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
303 KB
Volume
141
Category
Article
ISSN
0920-5861

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✦ Synopsis

Scheme 1. Reaction conditions for the epoxidation of trans-stilbene

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TRISPHAT salts of chiral iminium cations allow, in combination with 18-C-6, the use of biphasic CH 2 Cl 2 /water conditions, which can improve the enantioselectivity of the oxone-mediated epoxidation.