The iso-diameter growth of β-BaB 2 O 4 (BBO) crystals by the flux pulling method have been studied based on the phase equilibrium diagram in the BaB 2 O 4 -Na 2 O pseudo-binary system and from the interface stability. The mathematical expressions for the cooling rate in the growth of the crystals wi
Effect of the Temperature Fluctuation of the Melt on β-BaB2O4 (BBO) Crystal Growth
✍ Scribed by B.-G. Wang; A. Voigt; Z. -P. Lu
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 198 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0232-1300
No coin nor oath required. For personal study only.
✦ Synopsis
In this paper the effect of the growth temperature fluctuation, for instance, the transient furnace temperature variation due to a short-term electric power supply interruption on BBO crystal growth was investigated based on the theory of temperature wave transmitting in melt and the boundary layer theory of melt. It was found that the critical width of the temperature pulse to avoid the temperature wave penetrating through the boundary layer and reaching to the growth interface at a constant rotation speed (9~4 r/min) is 69~150 s and the corresponding amplitude of the temperature pulse is high more than 60 °C due to the large thickness of the velocity boundary layer of the melt. This result indicates that a small transient temperature fluctuation has no significant effect on the crystal quality, and therefore implies that not only transport processes but interface growth kinetics, a two-dimensional nucleation growth mode at the interface may also dominate the crystal growth.
📜 SIMILAR VOLUMES
Growth rates of boric acid have been measured both in the absence and in the presence of electrical field at 1.00 DC voltage as a function of supersaturation in a laboratory-scale fluidized bed crystallizer at the temperature range of 20 °C to 52 °C. The values of overall rate coefficient (K G ), di
While bulk crystallization from impure solutions is used industrially as a purification step for a wide variety of materials, it is a technique that has rarely been used for proteins. Proteins have a reputation for being difficult to crystallize and high purity of the initial crystallization solutio