Effect of the sulfide group on photopolymerization kinetics of di(meth)acrylates
β Scribed by Ewa Andrzejewska
- Book ID
- 104708924
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 455 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
The kinetics of photoinitiated polymerization of six analogous di(meth)acrylates and diacrylates was analysed according to the autocatalytic model (where is polymerization rate, p is conversion degree, R p \ kpm(1 [ p)n R p k is reaction rate constant and m and n are exponents), in order to Γnd the
The photopolymerization of several di-and tetrafunctional (meth)acrylic monomers in the presence of a styrene-butadiene-styrene polymeric matrix (SBS) has been studied. Electron spin resonance spectroscopy (ESR) and differential scanning photocalorimetry (photo-DSC) were used as monitoring technique
## Abstract **Summary:** A comprehensive oneβdimensional photopolymerization model was utilized to investigate the effect of oxygen on the freeβradical photopolymerization kinetics. The spatial profiling aspect of the model provided insight into the heterogeneity of the cure kinetics due to oxygen