Effect of the Structure of 2,2,2-Trinitroethyl-N-nitroamines on the Rate of Their Thermal Decomposition
โ Scribed by R. S. Stepanov; L. A. Kruglyakova; A. M. Astakhov
- Book ID
- 110325934
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2001
- Tongue
- English
- Weight
- 19 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1070-4280
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๐ SIMILAR VOLUMES
The thermal decomposition rate constant of AIBN ( k d ) in N,N-dimethylformamide (DMF)/ acrylonitrile (AN) mixtures of various compositions at 60ยฐC is studied. The k d value is (6.45 +. 0.3) X min-' for pure acrylonitrile. The k d values of DMF/AN mixtures were found to be dependent on the mixture
The thermal decomposition rate constant k d of 2,2'-azobis(isobutyronitrile) (AIBN) in ethyl acetate was determined at 60 ยฐC in the presence of various amounts of stannous octoate (SnOc 2 ). The k d values were found to be dependent on the concentration of SnOc 2 in the solution. This dependence is