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Effect of the polymer glass transition on the chromatographic retention volumes

✍ Scribed by J. S. Vrentas; C. M. Vrentas

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 63 KB
Volume: 97
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.21680

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## Abstract The free‐volume theory of diffusion is used to predict the effect of the glass transition on the concentration dependence of the solvent self‐diffusion coefficient at constant temperature. The theoretical prediction is in agreement with experimental data. © 2003 Wiley Periodicals, Inc.