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Effect of the nitrogen unshared electron pair on the direct13C-13C spin-spin coupling constant of a neighboring bond in oximes

โœ Scribed by V. V. Shcherbakov; L. B. Krivdin; G. A. Kalabin; B. A. Trofimov


Book ID
112445888
Publisher
Springer
Year
1986
Tongue
English
Weight
86 KB
Volume
35
Category
Article
ISSN
1573-9171

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Two-bond 13C-13C spin-coupling constants
โœ Timothy Church; Ian Carmichael; Anthony S. Serianni ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 465 KB

An empirical projection method is described to predict the magnitudes and signs of two-bond 13C-13C spin-coupling constants (2Jcc) in aldopyranosyl rings. The method has been applied primarily to the interpretation of 2Jcc c values, although the behavior of 2Jco c has also been examined in light of