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Effect of the nature of the cation and alkylating agent on the direction of ethylation of 1,3,3-triphenylpropyne salts in ether

✍ Scribed by P. I. Dem'yanov; I. B. Fedot'eva; V. S. Petrosyan; O. A. Reutov

Book ID
112445186
Publisher
Springer
Year
1984
Tongue
English
Weight
270 KB
Volume
33
Category
Article
ISSN
1573-9171

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We recently reported the synthesis of the methoxytrienes A and 2, potential precursors of the bridged trishomotropylium ion 2 1) . The low temperature lH-NMR spectrum of the cation produced by treatment of & with FS03H/S02ClF/CD2C12 (1:3:3) was not, however, consistent with either structure 2 or th