Effect of the medium on the rate of the degenerate rearrangement of 1,2,3,4,5-pentamethyl-1,3-cyclopentadiene
β Scribed by G. I. Borodkin; E. R. Susharin; M. M. Shakirov; V. G. Shubin
- Book ID
- 112446648
- Publisher
- Springer
- Year
- 1985
- Tongue
- English
- Weight
- 245 KB
- Volume
- 34
- Category
- Article
- ISSN
- 1573-9171
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## Abstract The title compound **1** is shown to give, both upon direct irradiation at 254 nm and upon acetophenoneβsensitized photolysis at 300 nm, the __syn__βvinylβpentamethylhousene **5**, which spontaneously rearranges in a [3,3]0sigmatropic process to give the bicyclo[3.2.0]heptadiene skeleto
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