Effect of the medium on polymerization of acrylonitrile
β Scribed by T.S. Yatsimirskaya; Yu.L. Spirin
- Book ID
- 118965255
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 416 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0032-3950
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## Abstract Micellar catalyzed polymerization of acrylonitrile using ceric(IV)βglycerol redox system in aqueous sulfuric acid solution in the presence of sodium lauryl sulfate (NaLS) has been studied. The polymerization experiments were conducted between 15Β°C and 25Β°C, under conditions where no oxi
## Abstract Application of shear is found to increase the rate of solution polymerization of acrylonitrile in N,Nβdimethyl formamide (DMF) initiated by benzoyl peroxide by as much as 400 percent of the value in absence of shear. The solvent DMF acts as an inert and maintains a homogeneous reaction