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Effect of the Environment on the Reactivity of 4′-Substituted Flavones and Isoflavones

✍ Scribed by Elaine A Armelin; Paulo Marcos Donate; Sergio E Galembeck

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
115 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis

AbstractÐThe reactivity of ¯avones and iso¯avones, substituted at the 4 H position by several types of electron-withdrawing or electrondonating groups, was studied by FMO theory in the gas-phase and in aqueous solution. The predictions of this theory were consistent with the experimental reactivity of analogue compounds, and also with the stability of the products of reaction of these compounds with different nucleophilic and electrophilic reagents. The preferences found in the gas-phase for the sites of reaction are retained in aqueous solution.

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