In contrast to the report in ref. 9, Kolthoff et al.t ~ did not take into account the effect of adsorption on the kinetic current (pre-wave) of the cobalt(ll)--cysteine complex.
Effect of the electrical double layer and pyridine adsorption on the catalytic polarographic current of nickel(II)-pyridine complexes
โ Scribed by Ya.I. Tur'yan; O.N. Malyavinskaya
- Publisher
- Elsevier Science
- Year
- 1969
- Weight
- 584 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0022-0728
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โฆ Synopsis
Since pyridine is regenerated during the complex reduction on the electrode, this pre-wave should more reasonably be referred to as a catalytic wave 2'3. * We have not carried out the catalytic pre-wave investigation in NaF solution as a complex formation effect 63 occurs between Ni 2 รท and F-.
๐ SIMILAR VOLUMES
The stopped-flow technique has been used to study the effect of cationic (CTAN), nonionic (Triton X-loo), and anionic (SDS) micelles on the rate of the reaction between nickel(I1) ion and the ligand pyridine-2-azo-p-dimethylaniline (PADA) at 20.0"C and ionic strength 0.03 mol dm-3. The complex forma
The electronic and EPR spectra of Cu(RC02)2 [R = (CH3)2CH-, C2Hg-,(CH3)$-] have been measured in pyridine-chlorobenzene solvent mixtures. The results have been interpreted in terms of equilibrium between mononuclear and binuclear forms of copper(l1) carboxylate complexes with pyridine. The dimerizat