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Effect of the Allyl Group in Reactions of Allyl Alcohol and Its Derivatives with ε-Caprolactam.

✍ Scribed by N. A. Storozhakova; V. B. Smirnov; A. I. Rakhimov


Publisher
John Wiley and Sons
Year
2003
Weight
103 KB
Volume
34
Category
Article
ISSN
0931-7597

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Directing Effect of a Neighboring Aromatic Group in the Cyclopropanation of Allylic Alcohols. -Various racemic allylic alcohols are stereoselectively transformed to cyclopropanes with I-CH 2 -Cl in the presence of either zinc or samarium reagent. Alcohols bearing an aryl group at the stereocenter a