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Effect of the addition of inert or TEMPO-capped prepolymer on polymerization rate and molecular weight development in the nitroxide-mediated radical polymerization of styrene

✍ Scribed by Martha Roa-Luna; Afsaneh Nabifar; Neil T. McManus; Eduardo Vivaldo-Lima; Liliane M. F. Lona; Alexander Penlidis


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
572 KB
Volume
109
Category
Article
ISSN
0021-8995

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Particle Size Effects in TEMPO-Mediated
✍ Tadashi Nakamura; Per B. Zetterlund; Masayoshi Okubo 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 122 KB

## Abstract **Summary:** 2,2,6,6‐Tetramethylpiperidinyl‐1‐oxy (TEMPO)‐mediated radical polymerization of styrene in aqueous miniemulsion at 125 °C using sodium dodecylbenzenesulfonate and poly(vinyl alcohol), respectively, as colloidal stabilizers has been investigated. The particle size had a dram