Effect of the A-site cation on methane oxidation of perovskite-type (La1−xMx)CoO3 (M=Ca, Sr, and Ba)
✍ Scribed by Hideki Taguchi; Keiko Matsu-ura; Masao Takada; Ken Hirota
- Book ID
- 113758598
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 551 KB
- Volume
- 190
- Category
- Article
- ISSN
- 0022-4596
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## Abstract Background The effect of the B cation on the surface properties and catalytic activity in the total combustion of toluene over La~1−x~Ca~x~BO~3~ (B = Fe,Ni) perovskite‐type oxides was studied. Result For the La~1−x~Ca~x~FeO~3~ series, the perovskite structure was maintained in the rang
The hexagonal perovskite-type oxides A x BO 3 (A ؍ Ca, Sr, Ba; B ؍ Co, Ni) consist of (BO 3 ) chains made up of face-sharing BO 6 octahedra and BO 6 trigonal prisms. On the basis of molecular orbital calculations for their structural building blocks we examined why the transition metal atoms in