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Effect of Temperature, Pressure, Acidity and Solvent on an Aquo Ion Exchange Reaction

✍ Scribed by Hunt, H. R.; Taube, H.


Book ID
127035725
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
691 KB
Volume
80
Category
Article
ISSN
0002-7863

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The kinetics of the bromate ion-iodide ion-L-ascorbic acid clock reaction was investigated as a function of temperature and pressure using stopped-flow techniques. Kinetic results were obtained for the uncatalyzed as well as for the Mo(V1) and V(V) catalyzed reactions. While molybdenum catalyzes the