## Abstract The transport behavior of H~2~, N~2~, CO~2~ was studied for blends of an aliphatic copolyester with a copolyester‐polyurethane (PU) at various temperatures from 20 to 80°C. It was found that there was an abrupt change in slope near the melting point of the copolyester in Arrhenius plot
Effect of temperature on gas permeation of polymer blends. I. Poly(ethylene oxide)/copolyester–polyurethane
✍ Scribed by Guo Qipeng; Xu Hechang; Ma Dezhu
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 341 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
The transport behavior of H,, Nz, Oz, and CO,, was studied for blends of poly(ethy1ene oxide) (PEO) with a copolyester-polyurethane (PU) at various temperatures from 20 to 80°C. It was found that there was an abrupt change in slope or discontinuity around the melting point of PEO in Arrhenius plot of the permeability vs. temperature. The relationships between the logarithm of gas permeability and blend composition were strongly dependent on the temperature and showed very different shapes at temperature below and above the melting point of PEO. The activation energy of gas permeation for the blends had different values below and above the melting temperature of PEO.
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