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Effect of supporting electrolytes and cathode materials on the electro-copolymerization of acrylonitrile with methacrylic acid

✍ Scribed by Veena Vijayanathan; S. Venkatachalam; V.N. Krishnamurthy


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
323 KB
Volume
29
Category
Article
ISSN
0014-3057

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✦ Synopsis


Abstraet---Copolymers of acrylonitrile with methacrylic acid were synthesized electrochemically. The reaction system consisted of dimethyl formamide as solvent and various quarternary ammonium salts as supporting electrolytes. The influences of supporting electrolytes and electrode materials on the compositions of the copolymers were investigated. The copolymers were characterized by i.r., NMR and elemental analyses. Thermal decomposition studies of the polymer in air are also discussed.


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Radical copolymerlzations of 2-acryloyloxyethyl diethyl phosphate (ADP) with methyl methacrylate (MMA) and with styrene were carried out under various conditions. The reactivity ratios were determined by the method of Fineman-Ross. Under a given set of conditions, the reactivity of the acrylate term