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Effect of Successive Meso-Phenyl Substitution on the Dissociation Kinetics of Copper(II) Octaethylporphyrin

✍ Scribed by M. E. Klyueva; T. N. Lomova; E. E. Suslova; A. S. Semeikin


Book ID
111613108
Publisher
Springer
Year
2003
Tongue
English
Weight
105 KB
Volume
39
Category
Article
ISSN
0040-5760

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Substituent effect on the redox potentia
✍ Wu Guo-Zhang; Leung (Xiaoguang Liang) Hiu-Kwong; Gan Wei-Xing πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 639 KB

meso-Substituent effect on the redox properties of octaethylporphyrin and its zinc(lI) and copper(I1) complexes are investigated with cyclic volatmmetry. The El/2 values were observed to correlate linearly with Hammett's d, constant for the first and second oxidation reaction and the first reduction