Substituent effect on the redox potentia
β
Wu Guo-Zhang; Leung (Xiaoguang Liang) Hiu-Kwong; Gan Wei-Xing
π
Article
π
1990
π
Elsevier Science
π
French
β 639 KB
meso-Substituent effect on the redox properties of octaethylporphyrin and its zinc(lI) and copper(I1) complexes are investigated with cyclic volatmmetry. The El/2 values were observed to correlate linearly with Hammett's d, constant for the first and second oxidation reaction and the first reduction