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Effect of substitution on the yield of high-spin nitrenes in the photolysis of 2,6-diazidopyridines

✍ Scribed by Sergei V. Chapyshev; Richard Walton; Paul M. Lahti

Book ID
111730258
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
73 KB
Volume
10
Category
Article
ISSN
0959-9436

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In this study, the UV induced photochemical reactions of two 2H-azirines -methyl 2-chloro-3-methyl-2H-azirine-2-carboxylate (MCMAC) and methyl 3-methyl-2H-azirine-2-carboxylate (MMAC) -isolated in argon matrices are compared. For both compounds, irradiation with > 235 nm led to observation of two pr