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Effect of Substituents on the Thermal Decomposition of Diazirines: Experimental and Computational Studies

✍ Scribed by Liu, Michael T. H.; Choe, Yoong-Kee; Kimura, Masahiro; Kobayashi, Kaoru; Nagase, Shigeru; Wakahara, Takatsugu; Niino, Yasuyuki; Ishitsuka, Midori O.; Maeda, Yutaka; Akasaka, Takeshi


Book ID
127371614
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
186 KB
Volume
68
Category
Article
ISSN
0022-3263

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Experimental and computational studies o
✍ Hai Yu; Eric M. Kennedy; Md. Azhar Uddin; Simon P. Sullivan; Bogdan Z. Dlugogors πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 160 KB

## Abstract Thermal pyrolysis of halon 1211 (CBrClF~2~), diluted in nitrogen, in a tubular alumina reactor, has been studied over the temperature range of 773–1073 K at residence times from 0.3 to 2 s. At temperatures below 973 K, the major products were CCl~2~F~2~, CBr~2~F~2~, C~2~Cl~2~F~4~, C~2~B