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Effect of substituents on the homo-1,4 addition of difluorocarbene to norbornadienes

✍ Scribed by Charles W. Jefford; Phan Thanh Huy


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
239 KB
Volume
23
Category
Article
ISSN
0040-4039

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Ab initio study of substituent effect on
✍ Miquel SolΓ ; AgustΓ­ LledΓ³s; Miquel Duran; Juan BertrΓ‘n; Oscar N. Ventura πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 1009 KB

An ab initio 3-21G study of the direct addition of HF to C2H,F(4-,,, with n = 0 to 4, has been performed to investigate the effect of the substituent on the reaction. Geometry optimization of all charge-transfer complexes and transition states has been done. Standard analysis of activation energies