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Effect of substituents on silicon on cross-metathesis of vinylsilanes with 1-alkenes in the presence of ruthenium complexes

โœ Scribed by Bogdan Marciniec; Cezary Pietraszuk; Zenon Foltynowicz

Publisher
Elsevier Science
Year
1992
Weight
638 KB
Volume
76
Category
Article
ISSN
0304-5102

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Cross-metathesis of vinylsilanes carryin
Cross-metathesis of vinylsilanes carrying electron-withdrawing substituents with olefins in the presence of the second-generation Grubbs catalyst
โœ Cezary Pietraszuk; Bogdan Marciniec; Helmut Fischer ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 93 KB

The efficient cross-metathesis of vinylsilanes carrying electron-withdrawing substituents with various olefins is described. High yields and selectivities were obtained when styrene, 1-hexene, and selective functional allyl derivatives were used as the olefins.