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Effect of substituents on amineN-oxides on the rates of O-atom transfer to metal carbonyls

✍ Scribed by Jian-Kun Shen; Yi-Ci Gao; Qi-Zhen Shi; Fred Basolo


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
577 KB
Volume
401
Category
Article
ISSN
0022-328X

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✍ Helio G. Bonacorso; Miguel S. B. Caro; Nilo Zanatta; Marcos A. P. Martins 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 450 KB 👁 1 views

## Abstract The barriers to rotation about the C(O)N bond for 13 α‐alkyl‐ and α‐halo‐substituted __N__‐theyl‐__N__‐methylamides were determined by ^1^H NMR spectroscopy at coalescence temperature. Plots of Gibbs free energy (Δ__G__°) and Gibbs energy of activation (Δ__G__‡) values against Charton'