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Effect of substituents in controlling the rate of the intramolecular cycloaddition reaction of allyl-substituted 2H-azirines

✍ Scribed by Padwa, Albert; Carlsen, Per H. J.

Book ID
127089529
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
1006 KB
Volume
43
Category
Article
ISSN
0022-3263

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Substituent effects on the photolysis of
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In this study, the UV induced photochemical reactions of two 2H-azirines -methyl 2-chloro-3-methyl-2H-azirine-2-carboxylate (MCMAC) and methyl 3-methyl-2H-azirine-2-carboxylate (MMAC) -isolated in argon matrices are compared. For both compounds, irradiation with > 235 nm led to observation of two pr