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Effect of structural change in viologen acceptors on the rate of single electron transfer from tributylphosphine

โœ Scribed by Yasui, Shinro; Itoh, Kenji; Ohno, Atsuyoshi; Tokitoh, Norihiro

Book ID
119950221
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
141 KB
Volume
4
Category
Article
ISSN
1477-0520

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Electron transfer reactions between a disk-shaped donor and acceptor are theoretically studied. The reorganization energy and the first-order and the second-order rate constants are calculated and compared with those for the case of a spherical donor and acceptor. The energy gap dependence of the se