Effect of stereoisomerism on the mass spectra of substituted iridanes
β Scribed by D. Krauss; H. Von Der Eltz; M. Ernert
- Book ID
- 107771898
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 259 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0020-7381
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The mass spectra of a series of mefa-and para-substituted phenyl acetates have been examined. Substituent effects have been correlated with A(AP-IP) values and by using the Harrison and Chin approach. The bond-cleavage and rearrangement reactions of phenyl acetates are compared with the correspondin
Stereoelectronic factors allow facile CI' atom loss from the ero-6-chloro-2-norbornanone radical cation but not from the endo-6-epimer. The predominant primary reaction in the endo-6 and in the m o d and endo-5 compounds is HCI elimination. While C1' e l i n a t i o n occurs with skeletal reorganiza