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Effect of stereochemical and electronic factors on the breakdown and rearrangement of 2-azidovinyl ketones

✍ Scribed by A. N. Nesmeyanov; M. I. Rybinskaya; T. G. Kelekhsaeva


Book ID
112433319
Publisher
Springer
Year
1969
Tongue
English
Weight
375 KB
Volume
18
Category
Article
ISSN
1573-9171

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Mass spectometry in structural and stere
✍ Wayne Carpenter; A. M. Duffield; Carl Djerassi πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 365 KB

The mass spectra of aliphatic ketones are drastically altered following substitution of a trifluoromethyl entity adjacent to the carbonyl group (I1 and 111) or attachment to the y-carbon atom (V). Loss of the trifluoromethyl group by a-cleavage far exceeds the alternative elimination OF an alkyl rad