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Effect of stabilizers in the thermal treatment of PVC—XVI: Study of the stabilization efficiency of antimony tris(isooctyl thioglycolate) in PVC

✍ Scribed by Z. Vymazal; Z. Vymazalová; K. Volka; T. Gögh; M. Karvaš


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
349 KB
Volume
20
Category
Article
ISSN
0014-3057

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✦ Synopsis


Antimony tris(isooctyl thioglycolate) [Sb(IOTG)3 ] is a powerful thermal stabilizer for PVC, particularly if added in quantities up to 2% (m/m) with respect to PVC. During the stabilizing action, (IOTG)2SbC1 is formed while the rate of elimination of HCI from the polymer decreases appreciably. The thermal degradation is accelerated as (IOTG)SbClz appears. During long-term heat treatment of PVC mixtures stabilized with Sb(IOTG)3, the organoantimony compound decomposes and its activity decreases.


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