The effect of covalency on the spinβorbi
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R. Al-Mobarak; Keith D. Warren
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Article
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1973
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Elsevier Science
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English
β 295 KB
It is shown that the spin-orbit coupling constant, f, far a series of 3d transition metal ions may be rtkfzctoriIy evaluated using approximate double-zeta SCF functions. The radial distance dependence of [ has been calculated, and the results indicate that the reduction of 4 below the free-ion value