Effect of some curatives on the properties of ethylene propylene diene rubber/polyethylene blends
✍ Scribed by Abdel-Bary, E M; von Soden, W; Pechhold, W
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 149 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0959-8103
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✦ Synopsis
A series of ethylene propylene diene rubber/polyethylene (EPDM/PE) blends has been prepared containing different weight fractions of PE up to 0.66. The blends were vulcanized with a sulphur system N-cyclohexyl-2-benzthiazol sulphenamide/sulphur (CBS/S), and a non-sulphursystem dicumyl peroxide (DCUP). The concentration of the latter has been changed from 1.5 phr up to 6 phr calculated on the total weight of the blend composition. It has been found that the maximum torque obtained from rheographs for blends vulcanized with the CBS/S system decreases markedly with increasing PE concentration in comparison with those vulcanized with peroxide. The E modulus obtained from the stress±strain diagram at 110 °C showed the role played by the crosslinking of PE, the E modulus for blends vulcanized by peroxide being higher than for samples vulcanized with CBS/S. In contrast, the values of E modulus of both samples are practically the same at room temperature and attain more than 40 MPa depending on the composition. The tensile strength at room temperature strongly increases with increasing the weight fraction of PE. It has also been con®rmed that the melting point of the crystalline phase of PE decreases with increasing crosslinking density of PE. The shear modulus obtained from dynamic mechanical measurements is in accordance with that obtained from static mechanical measurements.
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