Effect of Solvent Polarity, pH, and Metal Complexation on the Triple Fluorescence of 4-( N -1,4,8,11-tetraazacyclotetradecyl)benzonitrile
โ Scribed by Collins, Greg E.; Choi, Ling-Siu; Callahan, John H.
- Book ID
- 127152021
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 108 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The interaction of solvents and of unidentate ligands such as N, SCN^โ^, OCN^โ^ and OH^โ^ with the Co^2+^โ, Ni^2+^ and Cu^2+^โcomplexes of 1,4,8,11โtetramethylโ1,4,8,11โtetraazacyclotetradecane (TMC) have been studied by Spectrophotometric and calorimetric techniques. The spectra in dif
## Abstract The two macrocycles 1โ(2โaminoethyl)โ and 1โ[2โ(dimethylamino)ethyl]โ4, 8, 11โtrimethylโ1, 4, 8, 11โtetraazacyclotetradecane, **1** and **2**, respectively, and their metal complexes with Co^2+^, Ni^2+^ and Cu^2+^ were prepared. The different spectral properties of the complexes with th