✦ LIBER ✦

Effect of side groups on dynamics of polymer chains

✍ Scribed by Zhang Linxi

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 376 KB
Volume: 31
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(95)00057-7

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✦ Synopsis

The dynamics of polymer chains, such as +-A-BR-BR jX, are investigated by means of the equivalent linear polymer chains, $-A-B'-B'+-X, with the probability p of movement of bead B'. It is found that the relaxation times of the equivalent linear polymer chains obey the relation T,(p) = T,.p -Et, where & = 0.75, #& = #I3 = 0.85, in the absence of excluded volume, and T,(p) = T,.p-e (excluding k = l), where #& = p3 = 0.90, in the presence of excluded volume, where T, is the relaxation times T, of linear Polymer chains, or Tko = Tk (p = 1 .O).

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